2014年7月30日 Here we identify molybdenum disulphide as a promising cost-effective substitute for noble metal catalysts. We uncover that molybdenum disulphide shows
Production of methanol from anthropogenic carbon dioxide (CO 2) is a promising chemical process that can alleviate both the environmental burden and the dependence on fossil
2021年11月25日 CO is a common product of the electrochemical reduction of CO2, but its formation mechanism remains elusive. Here, the authors present a unified mechanistic
Non-noble metal molecular catalysts mediating the electrocatalytic reduction of carbon dioxide are still scarce. This work reports the electrochemical reduction of CO2 to
2021年10月1日 Chemical composition and crystal structure of different molybdenum carbide and nitride nanowires were determined by XRD ().The fourth diffractogram
2019年7月15日 Carbon dioxide is a greenhouse gas, and needs to be converted into one of the useful feedstocks, such as carbon monoxide and methanol. We demonstrate the reduction of CO 2 with H 2 as a reducing
2019年8月27日 With reference to the molybdenum complex 3a an IR absorption (nujol mull) centered at ca. 1700 cm −1 can be taken as an indication of κ 2-C,O coordination of
molybdenum processing, preparation of the ore for use in various products. Molybdenum (Mo) is a white platinum-like metal with a melting point of 2,610 °C (4,730 °F). In its pure
2022年2月22日 The level of carbon dioxide in the atmosphere has increased in a dangerous way during the past century. Methods to decrease this level are therefore of
2014年7月30日 Here we identify molybdenum disulphide as a promising cost-effective substitute for noble metal catalysts. We uncover that molybdenum disulphide shows superior carbon dioxide reduction performance
2021年8月18日 Carbon dioxide (CO2) is one of the main causes of global warming, with the burning of fossil fuels being the main source of anthropogenic CO2. For this reason, the capture and reduction of CO2 to value-added chemicals powered by renewable energy sources is on the forefront of electrocatalyst and photocatalyst research. The choice of
Production of methanol from anthropogenic carbon dioxide (CO 2) is a promising chemical process that can alleviate both the environmental burden and the dependence on fossil fuels.In catalytic CO 2 hydrogenation to methanol, reduction of CO 2 to intermediate species is generally considered to be a crucial step. It is of great significance to design and
2021年10月1日 Chemical composition and crystal structure of different molybdenum carbide and nitride nanowires were determined by XRD ().The fourth diffractogram (green line) shows Mo 2 C phase (JCPDS card no. 00-035-0787) obtained by carburization of MoSI NWs in a mixture of argon/ethane/hydrogen at 710 °C for several hours, followed by a
2021年12月17日 Three crystalline heterometallic molybdenum(V) phosphates have been synthesized under hydrothermal conditions. They all contain {M[P4Mo6O28(OH)3]2}16– [M = Mn(II) or Co(II)]
2015年12月21日 Here we describe a molybdenum compound, supported by a terphenyl–diphosphine ligand, that activates and cleaves the strong carbon–oxygen bond of carbon monoxide, enacts carbon–carbon
molybdenum processing, preparation of the ore for use in various products. Molybdenum (Mo) is a white platinum-like metal with a melting point of 2,610 °C (4,730 °F). In its pure state, it is tough and ductile and is characterized by moderate hardness, high thermal conductivity, high resistance to corrosion, and a low expansion coefficient. When alloyed
2023年4月23日 Carbon dioxide has long been blamed for the global warming and climate change. [17-23] transition metals, and their oxides, [24-35] molybdenum carbides/sulfides, [36-39] metal-organic complexes, [40-42] noble metals and their oxides/phosphides, In the process of CO 2 reduction reaction, the reaction free energy of Equation is negative
2022年2月22日 The level of carbon dioxide in the atmosphere has increased in a dangerous way during the past century. Methods to decrease this level are therefore of high interest at present. Inspiration to do so in an efficient way could come from biological systems. Molybdenum-containing formate dehydrogenase (Mo-FDH) is one of the most
2021年9月1日 This review highlights the recent advances of polyoxometalates (POMs)-based photocatalysts for carbon dioxide (CO 2) reduction, focusing on the roles of POMs, including roles as photocatalysts, cocatalysts, photosensitizers, and multi-electron donors, in the process of CO 2 photoreduction. The review will serve as a beacon of light on the
2014年7月30日 Here we identify molybdenum disulphide as a promising cost-effective substitute for noble metal catalysts. We uncover that molybdenum disulphide shows superior carbon dioxide reduction performance
2021年8月18日 Carbon dioxide (CO 2) is one of the main causes of global warming, with the burning of fossil fuels being the main source of anthropogenic CO 2.For this reason, the capture and reduction of CO 2 to value-added chemicals powered by renewable energy sources is on the forefront of electrocatalyst and photocatalyst research. The choice of
Production of methanol from anthropogenic carbon dioxide (CO 2) is a promising chemical process that can alleviate both the environmental burden and the dependence on fossil fuels.In catalytic CO 2 hydrogenation to methanol, reduction of CO 2 to intermediate species is generally considered to be a crucial step. It is of great significance to design and
2021年12月17日 Three crystalline heterometallic molybdenum(V) phosphates have been synthesized under hydrothermal conditions. They all contain {M[P4Mo6O28(OH)3]2}16– [M = Mn(II) or Co(II)]
2015年12月21日 Here we describe a molybdenum compound, supported by a terphenyl–diphosphine ligand, that activates and cleaves the strong carbon–oxygen bond of carbon monoxide, enacts carbon–carbon
2022年2月22日 The level of carbon dioxide in the atmosphere has increased in a dangerous way during the past century. Methods to decrease this level are therefore of high interest at present. Inspiration to do so in an efficient way could come from biological systems. Molybdenum-containing formate dehydrogenase (Mo-FDH) is one of the most
molybdenum processing, preparation of the ore for use in various products. Molybdenum (Mo) is a white platinum-like metal with a melting point of 2,610 °C (4,730 °F). In its pure state, it is tough and ductile and is characterized by moderate hardness, high thermal conductivity, high resistance to corrosion, and a low expansion coefficient. When alloyed
2023年4月23日 Carbon dioxide has long been blamed for the global warming and climate change. [17-23] transition metals, and their oxides, [24-35] molybdenum carbides/sulfides, [36-39] metal-organic complexes, [40-42] noble metals and their oxides/phosphides, In the process of CO 2 reduction reaction, the reaction free energy of Equation is negative
2021年9月1日 This review highlights the recent advances of polyoxometalates (POMs)-based photocatalysts for carbon dioxide (CO 2) reduction, focusing on the roles of POMs, including roles as photocatalysts, cocatalysts, photosensitizers, and multi-electron donors, in the process of CO 2 photoreduction. The review will serve as a beacon of light on the
2017年1月17日 CO2 (dry) reforming of methane (DRM) has received much attention as an important process for the transformation and applications of two greenhouse gases (CH4 and CO2). In the present study, non